Kinetic Theory of Gases - Topic 3.2

Bite-sized Kinetic Theory of Gases Study Notes for IB Physics HL/SL 

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Table of Contents

Kinetic Theory of Gases

Key point

  • The number of particles in a mole is equal to the Avogadro Constant
One mole of something contains as many particles as there are atoms in 12g of Carbon-12.
  • A ‘particle’ can mean an atom or a molecule
  • The number of particles in a mole is N A

Formula Booklet

Avogadro's Constant

Formula Booklet

Number of Particles Formula/Equation IB

If a substance contains N particles, then the number of moles ‘n‘ is given by this formula.

  • n = number of moles
  • N = Number of particles
  • NA = Avogadro’s Constant

The atomic mass unit (1u) is defined as 1/12 of the mass of a carbon-12 atom.

  • The mass per one neutron is 1 mole
  • The mass per one proton is 1 mole
  • Molar mass is the sum of all atomic masses of a molecule

Not in Formula Booklet but important

Nuclear Notation

Formula Booklet

Unified atomic mass unit

Unified atomic mass unit

Key point

  • Pressure is the normal force applied per unit area
Pressure is defined as the normal force applied per unit area.
  • The force is applied normal to the area
  • If the force is given by with an angle, then find the vertical component of the angle
  • P = Pressure
  • F = Force
  • A = Area
  • Unit: Newton per square metre, Nm-2 = pascal, Pa
  • Can also be used: atmospere, atm = 1.013 x 105 Pa

Formula Booklet

Pressure Formula IB

Key points

  • An ideal gas is a theoretical model of a real gas
  • A real gas can be approximated by an ideal gas at low density (low pressure, high temperature)

An Ideal Gas is a theoretical model of a gas. It is defined by the following assumptions: 

  • The molecules are point particles – with negligible volume
  • The molecules obey the laws of mechanics
  • An ideal gas can not be liquefied or solidified
  • Molecules have a variety of speeds and move randomly
  • There are no forces between the molecules except when the molecules collide
  • The duration of a collision is negligible compared to the time between collisions
  • The collisions of the molecules with each other and with the container walls are elastic

At very low density (low pressure, high temperature) a real gas will generally behave like an ideal gas. 

Key point

  • Pressure is inversely proportional to volume

The Pressure-Volume Law states that at constant temperature and with a fixed quantity of gas, pressure is inversely proportional to volume.  

  • This relationship is also known as Boyle’s Law
  • The curve is isothermal – the temperature at all points on the curve is the same
  • The product pV is the same for all points on the curve

Not in Formula Booklet but important

Pressure Volume Law Equations IB
Pressure Volume Law

Key point

  • Volume increases uniformly with temperature

The Volume-Temperature Law states that when temperature is expressed in kelvin, then at constant temperature volume increases uniformly with temperature. 

  • Charle’s Law

Not in Formula Booklet but important

Volume Temperature Law
Volume Temperature Law

Key point

  • Pressure increases uniformly with increasing temperature

The Pressure-Temperature Law states that when temperature is expressed in kelvin and volume is constant, then pressure increases uniformly with increasing temperature.

  • Gay-Lussac’s Law or Amonton’s Law

Not in Formula Booklet but important

Pressure Temperature Law
Pressure Temperature Law

Key point

  • The Gas constant (R) is a universal constant

The Equation of state of an Ideal Gas relates Volume, Pressure, Temperature, and the number of moles of a gas. .

  • is the universal gas constant
  • p = pressure
  • V = Volume
  • n = number of moles
  • T = temperature
  • Through the introduction of the universal gas constant one can now calculate for the missing quantities (with the help of the given quantities) 

Formula Booklet

Equation of state of an ideal gas

Key points

  • Calculate the Kinetic Energy of a gas
  • The Internal Energy of an ideal gas consists only of its kinetic energy

The molecules of a gas move randomly with a range of speeds.

  • kb = Boltzmann constant
  • T = Temperature
  • EK = Kinetic Energy

Formula Booklet

Kinetic Energy of a gas Formula/Equation IB
Boltzmann constant

Not in Formula Booklet but important

Internal Energy of an ideal gas Equation/Formula IB

The Internal Energy of an ideal gas consists only of the random kinetic energy of its molecules

  • N = Number of Molecules
  • kB = Boltzmann constant
  • T = Temperature
  • Remember the basic rules that characterize an ideal gas

Worksheet - Kinetic Molecular Theory of Gases

Worksheet with Answers

Questions and Answers

Worksheet with Answers 2.0

Questions and Answers

PPT (PDF) - Kinetic Molecular Theory of Gases

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